Selected isotope ratio measurements of light metallic elements (Li, Mg, Ca, and Cu) by multiple collector ICP-MS
نویسندگان
چکیده
The unique capabilities of multiple collector inductively coupled mass spectrometry (MC-ICP-MS) for high precision isotope ratio measurements in light elements as Li, Mg, Ca, and Cu are reviewed in this paper. These elements have been intensively studied at the Geological Survey of Israel (GSI) and other laboratories over the past few years, and the methods used to obtain high precision isotope analyses are discussed in detail. The scientific study of isotopic fractionation of these elements is significant for achieving a better understanding of geochemical and biochemical processes in nature and the environment.
منابع مشابه
Isotope ratio measurements: new developments and applications.
After 2004 and 2008 (Vols. 378/2 and 390/2) this is the third issue of Analytical and Bioanalytical Chemistry to contain papers on new developments and applications in isotope ratio measurements. Whereas Klaus Heumann was guest editor for the two previous special issues, in this issue Torsten Schmidt joins him as guest editor for the first time. His involvement with this collection of papers st...
متن کاملThe performance of single and multi-collector ICP-MS instruments for fast and reliable 34S/32S isotope ratio measurements†
The performance and validation characteristics of different single collector inductively coupled plasma mass spectrometers based on different technical principles (ICP-SFMS, ICP-QMS in reaction and collision modes, and ICP-MS/MS) were evaluated in comparison to the performance of MC ICP-MS for fast and reliable S isotope ratio measurements. The validation included the determination of LOD, BEC,...
متن کاملCu Purification Using an Extraction Resin for Determination of Isotope Ratios by Multicollector ICP-MS
A new simple and quick method has been established for separation of Cu from solutions using an extraction chromatographic resin utilizing Aliquat 336 (commercially available as TEVATM resin) and Cu(I). This method involves the use of a one milliliter column containing 0.33 mL TEVATM resin on 0.67 mL Amberchrom CG-71C acrylic resin. Copper was adsorbed on the column by forming Cu(I) with 0.15% ...
متن کاملReduction of UH formation for U/U isotope ratio measurements at ultratrace level in double focusing sector field ICP-MS using D2O as solvent
The main factors affecting the accurate and precise determination of U using ICP-MS are instrumental background, the isobaric interference of UH molecular ion on U analyte ions, and the presence of U and U peak tails. An optimized analytical method for attenuating the influence of these factors on uranium isotope ratio measurements at ultratrace level of environmental samples has been developed...
متن کاملQuantification of chemical elements in blood of patients affected by multiple sclerosis.
Although some studies suggested a link between exposure to trace elements and development of multiple sclerosis (MS), clear information on their role in the aetiology of MS is still lacking. In this study the concentrations of Al, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Hg, Li, Mg, Mn, Mo, Ni, Pb, Sb, Si, Sn, Sr, Tl, V, W, Zn and Zr were determined in the blood of 60 patients with MS and 60 control...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Analytical and Bioanalytical Chemistry
دوره 390 شماره
صفحات -
تاریخ انتشار 2008